Mechanistic aspects regarding the formation of metal vinylidenes from alkynes and related reactions

被引：139

作者：

Wakatsuki, Y ^{[1
]}

机构：

[1] RIKEN, OM Chem Tech Co Ltd, Wako, Saitama 3510198, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2004年 / 689卷 / 24期

关键词：

D O I：

10.1016/j.jorganchem.2004.05.052

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

This review focuses on the tautomerization mechanism between alkynes and vinylidene units taking place in the coordination sphere of transition metal fragments. Reactions of vinylidene complexes as well as catalytic reactions involving a metal-vinylidene intermediate are also reviewed from the mechanistic point of view. (C) 2004 Elsevier B.V. All rights reserved.

引用

页码：4092 / 4109

页数：18

共 84 条

[11] Selective transformations of alkynes with ruthenium catalysts [J].

Bruneau, C ;

Dixneuf, PH .

CHEMICAL COMMUNICATIONS, 1997, (06) :507-512

[12] Metal vinylidenes in catalysis [J].

Bruneau, C ;

Dixneuf, PH .

ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (04) :311-323

[13] REARRANGEMENT OF A METAL (ETA-2-ALKYNE) COMPLEX TO A METAL VINYLIDENE AND SUBSEQUENT REACTION OF THE METAL VINYLIDENE TO REGENERATE THE ALKYNE [J].

BULLOCK, RM .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1989, (03) :165-167

[14] First X-ray characterization and theoretical study of π-alkyne, alkynyl-hydride, and vinylidene isomers for the same transition metal fragment [Cp*Ru(pEt3)2] [J].

Bustelo, E ;

Carbó, JJ ;

Lledós, A ;

Mereiter, K ;

Puerta, MC ;

Valerga, P .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (11) :3311-3321

[15] Analysis of the solid-state rearrangement of hydrido-alkynyl ruthenium complexes to their vinylidene tautomers [J].

Bustelo, E ;

de los Ríos, I ;

Tenorio, MJ ;

Puerta, MC ;

Valerga, P .

MONATSHEFTE FUR CHEMIE, 2000, 131 (12) :1311-1320

[16] Reactivity of indenyl-ruthenium(II) vinylidene complexes:: Selective synthesis of alkenyl-phosphonio derivatives via nucleophilic addition of triphenylphosphine on their η2-alkyne tautomers.: Theoretical study of the η1-vinylidene-η2-alkyne tautomerization [J].

Cadierno, V ;

Gamasa, MP ;

Gimeno, J ;

González-Bernardo, C ;

Pérez-Carreño, E ;

García-Granda, S .

ORGANOMETALLICS, 2001, 20 (24) :5177-5188

[17] CATIONIC ACETYLENIC PLATINUM(II) COMPOUNDS AND THEIR DERIVATIVES .3. REACTIONS OF PLATINUM(II) STABILIZED CARBONIUM-IONS [J].

CHISHOLM, MH ;

CLARK, HC .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1972, 94 (05) :1532-&

[18] ELECTRON-TRANSFER-INDUCED INTERCONVERSION OF ALKYNE AND VINYLIDENE CHROMIUM COMPLEXES - A QUANTITATIVE STUDY [J].

CONNELLY, NG ;

GEIGER, WE ;

LAGUNAS, MC ;

METZ, B ;

RIEGER, AL ;

RIEGER, PH ;

SHAW, MJ .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (49) :12202-12208

[19] Density functional study of alkyne to vinylidene rearrangements in [(Cp)(PMe3)2Ru(HCCR)]+ (R = H, Me) [J].

De Angelis, F ;

Sgamellotti, A ;

Re, N .

ORGANOMETALLICS, 2002, 21 (26) :5944-5950

[20] Dynamical density functional study of acetylene to vinylidene isomerization in (Cp)(CO)2Mn(HC=CH) [J].

De Angelis, F ;

Sgamellotti, A ;

Re, N .

ORGANOMETALLICS, 2002, 21 (13) :2715-2723

← 1 2 3 4 5 6 7 8 9 →