The Pd(II) complex of a N,N'-diallylbenzimidazol-2-ylidene ligand

被引：38

作者：

Hahn, FE ^{[1
]}

Holtgrewe, C ^{[1
]}

Pape, T ^{[1
]}

机构：

[1] Univ Munster, Inst Anorgan & Analyt Chem, D-48149 Munster, Germany

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2004年 / 59卷 / 09期

关键词：

benzimidazol-2-ylidene; palladium(II); crystal structure; allyl groups;

D O I：

10.1515/znb-2004-0917

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The palladium(II) dicarbene complex trans- [PdBr2(L)(2)], 2 (L = 1,3-di-(2-propenyl)-benzimidazol-2-ylidene) was synthesized from 1,3-di-(2-propenyl)-benzimidazolium bromide 1 and Pd(OAc)(2) by in situ deprotonation. The X-ray structure analysis revealed a mononuclear complex with a palladium(II) center coordinated in a square-planar fashion by the two carbene functions and two bromo ligands.

引用

页码：1051 / 1053

页数：3

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