Catalytic carbon-fluorine bond activation with monocoordinated nickel-carbene complexes: reduction of fluoroarenes

被引：101

作者：

Kuhl, S ^{[1
]}

Schneider, R ^{[1
]}

Fort, Y ^{[1
]}

机构：

[1] Univ Nancy 1, Lab Synth Organ & React, UMR CNRS UHP 7565, F-54506 Vandoeuvre Les Nancy, France

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2003年 / 345卷 / 03期

关键词：

catalysis; fluoroarenes; nickel(O)/N-heterocyclic carbene complex; reduction;

D O I：

10.1002/adsc.200390036

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Monocoordinate nickel/N-heterocyclic carbene complexes reveal unexpected reactivity towards aryl fluorides. Defluorination reactions were efficiently performed with a beta-hydrogen-containing alkoxide (3 equiv.) in the presence of 3 mol % of [1:1] Ni(O)/IMes . HCI catalyst (IMes = 1,3-dimesitylimidazol-2-ylidene).

引用

页码：341 / 344

页数：4

共 35 条

[1] HOMOGENEOUS METAL-CATALYZED HYDROGENOLYSIS OF C-F BONDS [J].

AIZENBERG, M ;

MILSTEIN, D .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (33) :8674-8675

[2] CATALYTIC ACTIVATION OF CARBON-FLUORINE BONDS BY A SOLUBLE TRANSITION-METAL COMPLEX [J].

AIZENBERG, M ;

MILSTEIN, D .

SCIENCE, 1994, 265 (5170) :359-361

[3] DIBENZO[A,E]CYCLOOCTATETRAENE IN A PROPOSED TEST FOR HETEROGENEITY IN CATALYSTS FORMED FROM SOLUBLE PLATINUM GROUP METAL-COMPLEXES [J].

ANTON, DR ;

CRABTREE, RH .

ORGANOMETALLICS, 1983, 2 (07) :855-859

[4]

Arduengo A. J., 1991, U. S. Patent, Patent No. [5,077,414, 5077414]

[5] Imidazolylidenes, imidazolinylidenes and imidazolidines [J].

Arduengo, AJ ;

Krafczyk, R ;

Schmutzler, R ;

Craig, HA ;

Goerlich, JR ;

Marshall, WJ ;

Unverzagt, M .

TETRAHEDRON, 1999, 55 (51) :14523-14534

[6]

Böhm VPW, 2001, ANGEW CHEM INT EDIT, V40, P3387

[7] Catalytic C-F activation of polyfluorinated pyridines by nickel-mediated cross-coupling reactions [J].

Braun, T ;

Perutz, RN ;

Sladek, MI .

CHEMICAL COMMUNICATIONS, 2001, (21) :2254-2255

[8]

Braun T, 1999, ANGEW CHEM INT EDIT, V38, P3326, DOI 10.1002/(SICI)1521-3773(19991115)38:22<3326::AID-ANIE3326>3.0.CO

[9]

2-7

[10] Recent advances in C-F bond activation [J].

Burdeniuc, J ;

Jedlicka, B ;

Crabtree, RH .

CHEMISCHE BERICHTE-RECUEIL, 1997, 130 (02) :145-154

← 1 2 3 4 →