Ternary imides for hydrogen storage

被引:396
作者
Xiong, ZT [1 ]
Wu, GT [1 ]
Hu, HJ [1 ]
Chen, P [1 ]
机构
[1] Natl Univ Singapore, Dept Phys, Singapore 117542, Singapore
关键词
D O I
10.1002/adma.200400571
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ternary imides of Li-Mg and Li-Ca were synthesized and tested for hydrogen storage. Li2MgN2H2, as an example, reversibly stores 5.5 wt.-% hydrogen at temperatures below 180 degreesC (see Figure) with relatively high desorption plateau pressures. The present work also reveals the significance of chemical reactions between amides and ionic hydrides in the design and synthesis of novel metal-N-H systems for hydrogen storage.
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页码:1522 / +
页数:5
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