Parallels between the chemistry of calcium(II) and ytterbium(II). Synthesis and crystal structure of a calcium alkoxo-phosphide cuboidal complex

被引：40

作者：

Izod, K ^{[1
]}

Clegg, W ^{[1
]}

Liddle, ST ^{[1
]}

机构：

[1] Univ Newcastle Upon Tyne, Dept Chem, Newcastle Upon Tyne NE1 7RU, Tyne & Wear, England

来源：

ORGANOMETALLICS | 2000年 / 19卷 / 18期

关键词：

D O I：

10.1021/om000357b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Metathesis between CaI2 and K[P{CH(SiMe3)(2)}(C6H4-2-OMe)] in THF yields the alkoxophosphide complex [Ca{P(CH[SiMe3](2))(C6H4-2-O)}(THF)](4). 4THF (2) via a ligand cleavage reaction involving the migration of a methyl group from oxygen to phosphorus. Xray crystallography shows that 2 contains a Ca4O4 cuboidal core with mu(2)-phosphide groups bridging four of the faces of the cuboid.

引用

页码：3640 / 3643

页数：4

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