Sulphur isotope compositions of components of coal and S-isotope fractionation during its combustion and flue gas desulphurization

被引:20
作者
Derda, Malgorzata
Chmielewski, Andrzej Grzegorz
Licki, Janusz
机构
[1] Inst Nucl Chem & Technol, INC, PL-03195 Warsaw, Poland
[2] Inst Atom Energy, PL-05400 Otwock, Poland
关键词
desulphurization; flue gas; lignite; mass spectrometry; sulphur-34; power plant;
D O I
10.1080/10256010601153827
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Sulphur isotope compositions were determined in two different Polish coals ( hard coal and lignite) and by-products originating from their combustion. The desulphurization process was also investigated. It was demonstrated that desulphurization changes the isotopic composition of sulphur emitted in the form of SO2 to the atmosphere even if the process is conducted in a different way ( wet lime technology and electron beam method). This fact has to be considered in the studies regarding anthropogenic sulphur genesis and its fate in the environment.
引用
收藏
页码:57 / 63
页数:7
相关论文
共 24 条
[11]  
Hoefs J., 1997, STABLE ISOTOPE GEOCH, V4th ed.
[12]  
KROUSE HR, 1991, SCOPE, V443
[13]   Use of stable sulfur isotopes to identify sources of sulfate in Rocky Mountain snowpacks [J].
Mast, MA ;
Turk, JT ;
Ingersoll, GP ;
Clow, DW ;
Kester, CL .
ATMOSPHERIC ENVIRONMENT, 2001, 35 (19) :3303-3313
[14]  
MUKAI H, 2001, ENVIRON SCI TECHNOL, V36, P1054
[15]   Temporal trends in the isotope signature of air-borne sulfur in Central Europe [J].
Novák, M ;
Jacková, I ;
Prechová, E .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2001, 35 (02) :255-260
[16]   Cumulative impact of 40 years of industrial sulfur emissions on a forest soil in west-central Alberta (Canada) [J].
Prietzel, J ;
Mayer, B ;
Legge, AH .
ENVIRONMENTAL POLLUTION, 2004, 132 (01) :129-144
[17]   Sources of natural and anthropogenic sulphur around the Teruel power station, NE Spain. Inferences from sulphur isotope geochemistry [J].
Querol, X ;
Alastuey, A ;
Chaves, A ;
Spiro, B ;
Plana, F ;
Lopez-Soler, A .
ATMOSPHERIC ENVIRONMENT, 2000, 34 (02) :333-345
[18]   Biodesulfurization of coals of different rank:: Effect on combustion behavior [J].
Rubiera, F ;
Arenillas, A ;
Martínez, O ;
Moran, A ;
Fuente, E ;
Pis, JJ .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1999, 33 (03) :476-481
[19]   DISTRIBUTION AND ISOTOPIC COMPOSITION OF SULFUR IN COAL [J].
SMITH, JW ;
BATTS, BD .
GEOCHIMICA ET COSMOCHIMICA ACTA, 1974, 38 (01) :121-133
[20]   SO2 scrubbing technologies:: A review [J].
Srivastava, RK ;
Jozewicz, W ;
Singer, C .
ENVIRONMENTAL PROGRESS, 2001, 20 (04) :219-227