The synthesis, crystal structure and spectroscopic properties of a new two-dimensional silver(I) coordination network

被引：23

作者：

Fei, BL

Sun, WY ^{[1
]}

Zhang, YA

Yu, KB

Tang, WX

机构：

[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

[2] Chinese Acad Sci, Anal Ctr, Chengdu 610041, Peoples R China

来源：

INORGANICA CHIMICA ACTA | 2000年 / 306卷 / 01期

关键词：

crystal structures; silver complexes; tetradentate ligand complexes; hydrogen bonds;

D O I：

10.1016/S0020-1693(00)00143-2

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A flexible tetradentate ligand 1,6-bis(4'-pyridyl)-2,5-diazahexane (BPDH) reacts with tetrakis(acetonitrile)silver(I) tetrafluoroborate to form a novel two-dimensional network complex [Ag(BPDH)]BF(4). CH(3)CN. The compound crystallizes in monoclinic, space group P2(1)/n with a = 14.121(2), b = 7.0410(10), c = 19.803(3) Angstrom, beta = 94.700(10)degrees, V = 1962.3(5) Angstrom(3) and Z = 4. The solvate acetonitrile molecule and counter anions are incorporated in the channels formed between two adjacent sheets through C-H ... F, N-H ... F and N-H ... N hydrogen bonds. The spectroscopic properties of the complex as luminescent, thermogravimetric and electrospray mass spectrometry were also described. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：106 / 111

页数：6

共 35 条

[1] A NEW TYPE OF INFINITE 3D POLYMERIC NETWORK CONTAINING 4-CONNECTED, PERIPHERALLY LINKED METALLOPORPHYRIN BUILDING-BLOCKS
ABRAHAMS, BF
HOSKINS, BF
ROBSON, R
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1991, 113 (09) : 3606 - 3607
[2] BJORN A, 1985, ORGANOMETALLICS, V4, P1275
[3] From helicate to infinite coordination polymer: crystal and molecular structures of silver(I) complexes of readily prepared di-Schiff bases
Bowyer, PK
Porter, KA
Rae, AD
Willis, AC
Wild, SB
[J]. CHEMICAL COMMUNICATIONS, 1998, (10) : 1153 - 1154
[4] MULTIDIMENSIONAL CRYSTAL ENGINEERING OF BIFUNCTIONAL METAL-COMPLEXES CONTAINING COMPLEMENTARY TRIPLE HYDROGEN-BONDS
BURROWS, AD
CHAN, CW
CHOWDHRY, MM
MCGRADY, JE
MINGOS, DMP
[J]. CHEMICAL SOCIETY REVIEWS, 1995, 24 (05) : 329 - &
[5] 2D POLYMERIC SILVER(I) COMPLEXES CONSISTING OF MARKEDLY UNDULATED SHEETS OF SQUARES - X-RAY CRYSTAL-STRUCTURES OF [AG(PPZ)(2)](BF4) AND [AG(PYZ)(2)](PF6) (PPZ=PIPERAZINE, PYZ=PYRAZINE)
CARLUCCI, L
CIANI, G
PROSERPIO, DM
SIRONI, A
[J]. INORGANIC CHEMISTRY, 1995, 34 (22) : 5698 - +
[6] SUPRAMOLECULAR SYNTHONS IN CRYSTAL ENGINEERING - A NEW ORGANIC-SYNTHESIS
DESIRAJU, GR
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (21): : 2311 - 2327
[7] PREPARATION, CLATHRATION ABILITY, AND CATALYSIS OF A 2-DIMENSIONAL SQUARE NETWORK MATERIAL COMPOSED OF CADMIUM(II) AND 4,4'-BIPYRIDINE
FUJITA, M
KWON, YJ
WASHIZU, S
OGURA, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (03) : 1151 - 1152
[8] Fujita M, 1998, ANGEW CHEM INT EDIT, V37, P2082, DOI 10.1002/(SICI)1521-3773(19980817)37:15<2082::AID-ANIE2082>3.0.CO
[9] 2-0
[10] INTERPENETRATING MOLECULAR LADDERS AND BRICKS
FUJITA, M
KWON, YJ
SASAKI, O
YAMAGUCHI, K
OGURA, K
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (27) : 7287 - 7288

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