Probing inter-ligand excited state interaction in homo and heteroleptic ruthenium(II) polypyridyl complexes using selective deuteriation

被引：18

作者：

Browne, Wesley R.

Passaniti, Paolo

Gandolfi, Maria Teresa

Ballardini, Roberto

Henry, William

Guckian, Adrian

O'Boyle, Noel

McGarvey, John J.

Vos, Johannes G. ^{[1
]}

机构：

[1] Dublin City Univ, Sch Chem Sci, Natl Ctr Sensor Res, Dublin 9, Ireland

[2] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy

[3] Queens Univ Belfast, Sch Chem & Chem Engn, Belfast BT9 5AG, Antrim, North Ireland

来源：

INORGANICA CHIMICA ACTA | 2007年 / 360卷 / 03期

关键词：

ruthenium; polypyridyl; deuteriation; luminescence; lifetime; resonance Raman;

D O I：

10.1016/j.ica.2006.08.049

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The effect of deuteriation on the photophysical properties of two series of regioselectively deuteriated Ru(II) complexes ([Ru(bipy)(x)(ph(2)phen)(3-x)](2+), where x = 0-3 and ph(2)phen is 4,7-diphenyt-1,10-phenanthroline and [Ru(biPY)(2)(dcbipy(2-))], where H(2)dcbipy is 4,4'-dicarboxy-2,2'-bipyridyl) is reported. Although overall, deuteriation results in an increase in emission lifetime for all complexes, the effect of substitution of hydrogen for deuterium shows strong regioselectivity both in terms of the ligand and the position on individual ligands that are exchanged. (c) 2006 Elsevier B.V. All rights reserved.

引用

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页码：1183 / 1190

页数：8

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