Polymorphism and Reversible Mechanochromic Luminescence for Solid-State Difluoroboron Avobenzone

被引:757
作者
Zhang, Guoqing [1 ]
Lu, Jiwei [2 ]
Sabat, Michal [1 ]
Fraser, Cassandra L. [1 ]
机构
[1] Univ Virginia, Dept Chem, Charlottesville, VA 22904 USA
[2] Univ Virginia, Dept Mat Sci & Engn, Charlottesville, VA 22904 USA
基金
美国国家科学基金会;
关键词
CENTER-DOT-F; PHOTOLUMINESCENCE PROPERTIES; MOLECULAR PACKING; FLUORESCENCE; CRYSTALS; ASSEMBLIES; COMPLEXES; EMISSION; PLATINUM(II); DIFLUORIDES;
D O I
10.1021/ja9097719
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Difluoroboron avobenzone (BF(2)AVB), a simple boron complex of a commercial sunscreen product, exhibits morphology-dependent emission and mechanochromic the solid state. When scratched. smeared, or even gently touched, the emission color of BF(2)AVB films is significantly red-shifted Under UV excitation. In the rubbed regions, the florescence recovers slowly at room temperature Or much Faster with heating, resulting in a simple rewritable "scratch the surface" ink of potential commercial use.
引用
收藏
页码:2160 / +
页数:5
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