Enhancement of photocatalytic performance via a P3HT-g-C3N4 heterojunction

被引:168
作者
Bai, Xiaojuan [1 ,2 ]
Sun, Changpo [2 ]
Wu, Songling [2 ]
Zhu, Yongfa [1 ]
机构
[1] Tsinghua Univ, Beijing Key Lab Analyt Methods & Instrumentat, Dept Chem, Beijing 100084, Peoples R China
[2] Acad State Adm Grain, Beijing 100037, Peoples R China
基金
国家高技术研究发展计划(863计划); 美国国家科学基金会;
关键词
CARBON NITRIDE SEMICONDUCTORS; HYDROGEN-PRODUCTION; CHARGE-TRANSPORT; WATER; EVOLUTION; MORPHOLOGY; SPECTRA;
D O I
10.1039/c4ta04779f
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070305 [高分子化学与物理];
摘要
P3HT-g-C3N4 photocatalysts with high activity have been fabricated by assembling p-type P3HT particles on n-type g-C3N4 nanoplates via a ball milling method. The photocatalytic activity of the P3HT-g-C3N4 photocatalysts for the degradation of MB was 2 times higher than that of pure g-C3N4. The formation of a heterojunction interface of P3HT-g-C3N4 photocatalysts enhanced the separation efficiency of photogenerated electron-hole pairs and resulted in the enhancement of photocatalytic performance. The potential difference in the heterojunction is the main driving force for efficient charge separation and transfer.
引用
收藏
页码:2741 / 2747
页数:7
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