Transition-Metal-Catalyzed Synthesis of Hydroxylated Arenes

被引：191

作者：

Alonso, Diego A. ^{[1
,2
]}

Najera, Carmen ^{[1
,2
]}

Pastor, Isidro M. ^{[1
,2
]}

Yus, Miguel ^{[1
,2
]}

机构：

[1] Univ Alicante, Dept Organ Chem, E-03080 Alicante, Spain

[2] Univ Alicante, Inst Organ Synth, E-03080 Alicante, Spain

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2010年 / 16卷 / 18期

关键词：

C-H activation; homogeneous catalysis; hydroxylation; oxidation; phenols; C-O BOND; ARYL HALIDES; BENZOIC-ACIDS; H BONDS; OXIDATIVE FUNCTIONALIZATION; AROMATIC ACETOXYLATION; REDUCTIVE ELIMINATION; DIOXYGEN ACTIVATION; HYDROGEN-PEROXIDE; CARBON-HETEROATOM;

D O I：

10.1002/chem.201000470

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An overview of the recent bibliography in the transition-metal-catalyzed hydroxylation of aryl derivatives is presented. Two reaction protocols are considered: 1) C-H activation/hydroxylation and, 2) cross-coupling hydroxylation of aryl halides. The achievements and limitations for both procedures are described taking into consideration different metal catalyst/oxidant combinations.

引用

页码：5274 / 5284

页数：11

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