Facile dihydrogen release from phosphino-borinate ester Lewis pairs

被引：12

作者：

Chapman, Andy M. ^{[1
]}

Haddow, Mairi F. ^{[1
]}

Orton, Jonathan P. H. ^{[1
]}

Wass, Duncan F. ^{[1
]}

机构：

[1] Univ Bristol, Sch Chem, Bristol BS8 1TS, Avon, England

来源：

DALTON TRANSACTIONS | 2010年 / 39卷 / 27期

关键词：

FREE CATALYTIC-HYDROGENATION; METAL-FREE; ACTIVATION; HB(C6F5)(2);

D O I：

10.1039/c0dt00513d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

New phosphino-borinate ester Lewis pairs of the type (t)Bu(2)PCH(2)C(R)(2)OB(C(6)F(5))(2) (R = Me or CF(3)) are synthesised from the corresponding phosphino-alcohol and HB(C(6)F(5))(2). Dihydrogen release from the zwitterionic (t)Bu(2)PHCH(2)C(R)(2)OBH(C(6)F(5))(2) is facile.

引用

页码：6184 / 6186

页数：3

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