Homogeneous CO Hydrogenation: Dihydrogen Activation Involves a Frustrated Lewis Pair Instead of a Platinum Complex

被引：110

作者：

Miller, Alexander J. M. ^{[1
]}

Labinger, Jay A. ^{[1
]}

Bercaw, John E. ^{[1
]}

机构：

[1] CALTECH, Arnold & Mabel Beckman Labs Chem Synth, Pasadena, CA 91125 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2010年 / 132卷 / 10期

关键词：

HYDRIDE DONOR ABILITIES; CARBON-MONOXIDE; REACTIVITY; DESIGN;

D O I：

10.1021/ja100574n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

During a search for conditions appropriate for Pt-catalyzed CO reduction using dihydrogen directly, metal-free conditions were discovered instead. A bulky, strong phosphazene base forms a "frustrated" Lewis pair (FLP) with a trialkylborane in the secondary coordination sphere of a rhenium carbonyl. Treatment of the FLP with dihydrogen cleanly affords multiple hydride transfers and C C bond formation.

引用

页码：3301 / +

页数：4

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