Induced magnetism of carbon atoms at the graphene/Ni(111) interface

被引:171
作者
Weser, M. [1 ]
Rehder, Y. [1 ]
Horn, K. [1 ]
Sicot, M. [2 ]
Fonin, M. [2 ]
Preobrajenski, A. B. [3 ]
Voloshina, E. N. [4 ]
Goering, E. [5 ]
Dedkov, Yu. S. [1 ]
机构
[1] Max Planck Gesell, Fritz Haber Inst, D-14195 Berlin, Germany
[2] Univ Konstanz, Fachbereich Phys, D-78457 Constance, Germany
[3] Lund Univ, Max Lab, S-22100 Lund, Sweden
[4] Free Univ Berlin, Inst Chem & Biochem Phys & Theoret Chem, D-14195 Berlin, Germany
[5] Max Planck Inst Met Res, D-70569 Stuttgart, Germany
关键词
electronic structure; graphene; interface structure; magnetic circular dichroism; magnetic moments; nickel; valence bands; X-ray absorption spectra; RAY CIRCULAR-DICHROISM; ABSORPTION; GRAPHITE; NI; FILMS;
D O I
10.1063/1.3280047
中图分类号
O59 [应用物理学];
学科分类号
摘要
We report an element-specific investigation of electronic and magnetic properties of the graphene/Ni(111) system. Using x-ray magnetic circular dichroism, the occurrence of an induced magnetism of the carbon atoms in the graphene layer is observed. We attribute this magnetic moment to the strong hybridization between C pi and Ni 3d valence band states. The net magnetic moment of carbon in the graphene layer is estimated to be in the range of 0.05-0.1 mu(B) per atom.
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页数:3
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