Electrosynthesis of indium sulfide on sulfur-modified polycrystalline gold electrodes

被引：17

作者：

de Tacconi, NR ^{[1
]}

Rajeshwar, K ^{[1
]}

机构：

[1] Univ Texas, Dept Chem & Biochem, Arlington, TX 76019 USA

来源：

JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 1998年 / 444卷 / 01期

关键词：

semiconductor thin film; photoelectrochemistry; indium; electrodeposition;

D O I：

10.1016/S0022-0728(97)00533-0

中图分类号：

O65 [分析化学];

学科分类号：

070302 ; 081704 ;

摘要：

A new approach for the electrosynthesis of indium sulfide films is described. This approach uses a sulfur-modified gold substrate, and relies on the underpotential deposition of indium on it to form an indium sulfide alloy. Combined cyclic voltammetry and electrochemical quartz crystal microgravimetry scans demonstrate the veracity of this film growth approach. Photoelectrochemical measurements in a polysulfide redox medium show that the In2S3 layers thus grown are photoactive and behave as an n-type semiconductor. (C) 1998 Elsevier Science S.A. All rights reserved.

引用

页码：7 / 10

页数：4

共 16 条

[1] SYNTHESIS AND PHOTOELECTROCHEMISTRY OF IN2S3 [J].

BECKER, RS ;

ZHENG, T ;

ELTON, J ;

SAEKI, M .

SOLAR ENERGY MATERIALS, 1986, 13 (02) :97-107

[2] THERMODYNAMIC STABILITY OF NORMAL-IN2S3 PHOTOELECTRODES [J].

BICELLI, LP .

ELECTROCHIMICA ACTA, 1987, 32 (05) :777-783

[3] EFFICIENT ELECTROCATALYST ASSEMBLIES FOR PROTON AND OXYGEN REDUCTION - THE ELECTROSYNTHESIS AND CHARACTERIZATION OF POLYPYRROLE FILMS CONTAINING NANODISPERSED PLATINUM PARTICLES [J].

BOSE, CSC ;

RAJESHWAR, K .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1992, 333 (1-2) :235-256

[4] OVERLAYER FORMATION IN THE N-CDSE/[FE(CN)(6)](4-/3-) PHOTOELECTROCHEMICAL SYSTEM AS PROBED BY LASER RAMAN-SPECTROSCOPY AND ELECTROCHEMICAL QUARTZ-CRYSTAL MICROGRAVIMETRY [J].

DETACCONI, NR ;

MYUNG, N ;

RAJESHWAR, K .

JOURNAL OF PHYSICAL CHEMISTRY, 1995, 99 (16) :6103-6109

[5] CATHODIC ELECTROSYNTHESIS OF METAL SULFIDE THIN-FILMS AT A SULFUR-MODIFIED GOLD SURFACE - APPLICATION TO THE IRON SULFIDE SYSTEM [J].

DETACCONI, NR ;

MEDVEDKO, O ;

RAJESHWAR, K .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1994, 379 (1-2) :545-547

[6] DETERMINATION OF THE FLAT BAND POTENTIAL FOR IN2S3 ELECTROLYTE INTERFACES [J].

HERRASTI, P ;

FATAS, E ;

HERRERO, J ;

ORTEGA, J .

ELECTROCHIMICA ACTA, 1990, 35 (02) :345-349

[7] NORMAL-TYPE IN2S3 THIN-FILMS PREPARED BY GAS CHALCOGENIZATION OF METALLIC ELECTROPLATED INDIUM - PHOTOELECTROCHEMICAL CHARACTERIZATION [J].

HERRERO, J ;

ORTEGA, J .

SOLAR ENERGY MATERIALS, 1988, 17 (05) :357-368

[8] IR STUDIES OF LAYERED COMPOUND ZNIN2S4/IN2S4 [J].

HERRMANN, H .

PHYSICA STATUS SOLIDI B-BASIC SOLID STATE PHYSICS, 1977, 82 (02) :513-521

[9] PHOTOELECTROCHEMISTRY IN PARTICULATE SYSTEMS .7. ELECTRON-TRANSFER REACTIONS OF INDIUM SULFIDE SEMICONDUCTOR COLLOIDS [J].

KAMAT, PV ;

DIMITRIJEVIC, NM ;

FESSENDEN, RW .

JOURNAL OF PHYSICAL CHEMISTRY, 1988, 92 (08) :2324-2329

[10] MODULATED REFLECTANCE SPECTROSCOPY AND VOLTAMMETRY OF THE SULFIDE GOLD SYSTEM [J].

LEZNA, RO ;

DETACCONI, NR ;

ARVIA, AJ .

JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1990, 283 (1-2) :319-336

← 1 2 →