A gem-organodizinc species assembled in a tetrameric cage

被引：44

作者：

Andrews, PC

Raston, CL ^{[1
]}

Skelton, BW

White, AH

机构：

[1] Monash Univ, Dept Chem, Melbourne, Vic 3168, Australia

[2] Univ Western Australia, Dept Chem, Nedlands, WA 6907, Australia

来源：

ORGANOMETALLICS | 1998年 / 17卷 / 05期

关键词：

D O I：

10.1021/om970986u

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of both polymeric [{(2-pyridyl)-(SiMe3)C}SbCl](infinity) and the implied stibene (Sb=C) containing red oil, formed as a result of Me3SiCl elimination from [{(2-pyridyl)(SiMe3)(2)C}(2)SbCl], with excess Et2Zn in the presence of tmeda results in the geminal organodizinc chiral cage tetramer [Zn{C(SiMe3)(2-pyridyl)}](4) possessing three-coordinate metal centers, [(tmeda)Et-(Cl)Zn] and [(tmeda)Et2Zn].

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页码：779 / 782

页数：4

相关论文

共 18 条

[1] A gem-aluminium(III)/antimony(III) C centre incorporated in a bimetallic six-membered heterocycle [J].

Andrews, PC ;

Raston, CL ;

Skelton, BW ;

White, AH .

CHEMICAL COMMUNICATIONS, 1997, (13) :1183-1184

[2]

ANDREWS PC, 1998, IN PRESS CHEM COMMUN

[3] SYNTHESIS AND STRUCTURE OF COPPER(I), SILVER(I) AND ZINC(II) AMIDES [CU2(MPSA)2], [CU6X2(MPSA)4] (X = CL OR BR), [AG4(MPSA)4] AND [(ZNET)2(MPSA)2] [MPSA = 2-N(SIME3)-C5H3N-6-ME] [J].

ENGELHARDT, LM ;

JACOBSEN, GE ;

PATALINGHUG, WC ;

SKELTON, BW ;

RASTON, CL ;

WHITE, AH .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (11) :2859-2868

[4] ALKYLALUMINUM CATIONS - SYNTHESIS AND STRUCTURE OF [AL(2-C(SIME3)2C5H4N)2][ALCL4] [J].

ENGELHARDT, LM ;

KYNAST, U ;

RASTON, CL ;

WHITE, AH .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1987, 26 (07) :681-682

[5] SOLID-STATE AND SOLUTION STRUCTURE OF DILITHIUM TRIMETHYL((PHENYLSULFONYL)METHYL)SILANE, A TRUE DILITHIOMETHANE DERIVATIVE [J].

GAIS, HJ ;

VOLLHARDT, J ;

GUNTHER, H ;

MOSKAU, D ;

LINDNER, HJ ;

BRAUN, S .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (03) :978-980

[6] Synthesis and structure of ortho-phenylenezinc [J].

Goedheijt, MS ;

Nijbacker, T ;

Akkerman, OS ;

Bickelhaupt, F ;

Veldman, N ;

Spek, AL .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (13-14) :1550-1552

[7]

HALL SR, 1990, XTAL USERS MANUAL VE

[8] SYNTHESES AND STRUCTURES OF HIGHLY HINDERED N-FUNCTIONALIZED ALKYL GROUP-2 METAL-COMPLEXES [M(NC5H4C(SIME3)2-2)2] (M = MG, ZN, CD, OR HG) [J].

HENDERSON, MJ ;

PAPASERGIO, RI ;

RASTON, CL ;

WHITE, AH ;

LAPPERT, MF .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (09) :672-674

[9] THE 1ST X-RAY STRUCTURE OF A 1,1-DI-GRIGNARD COMPOUND - BIS(BROMOMAGNESIO)BIS(TRIMETHYLSILYL)METHANE [J].

HOGENBIRK, M ;

SCHAT, G ;

AKKERMAN, OS ;

BICKELHAUPT, F ;

SMEETS, WJJ ;

SPEK, AL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (18) :7302-7303

[10] ALKYLATION OF (AS, SB, BI)CL3 - FORMATION OF [(AS, SB, BI)RCL2], (E)-[BIR(CH2CH=C)(SIME3)(C5H4N-2)] AND 2-CH(SIME3)2C5H4N-5-R [R = C(SIME3)2C5H4N-2] [J].

JONES, C ;

ENGELHARDT, LM ;

JUNK, PC ;

HUTCHINGS, DS ;

PATALINGHUG, WC ;

RASTON, CL ;

WHITE, AH .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1991, (21) :1560-1562