Tetrakis[(9-oxo-10-thiaxanthen-2-yl-oxyethyl)ammonium] decaiodotriplumbate(II)

被引：8

作者：

Maxcy, KR ^{[1
]}

Willett, RD

Mitzi, DB

Afzali, A

机构：

[1] Washington State Univ, Dept Chem, Pullman, WA 99164 USA

[2] IBM Corp, Thomas J Watson Res Ctr, Yorktown Hts, NY 10598 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2003年 / 59卷

关键词：

D O I：

10.1107/S1600536803007414

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The structure of the title compound, (AETO)(4)[Pb3I10] or (C15H14NO2S)(4)[Pb3I10], contains chains of octahedrally coordinated PbI6 species along with two crystallographically independent AETO cations that hydrogen bond to these chains. Individual (Pb3I10)(n)(4n-). chains are linked into layers via hydrogen bonds. The cations sheath each layer of chains, forming cation-chain-cation triple layers. Cations on adjacent triple layers interdigitate, forming stacks running parallel to [110]. There is a range of hydrogen bonding interactions between each cation and the (Pb3I10)(n)(4n-). chains.

引用

页码：M364 / M366

页数：3

共 15 条

[1] The Cambridge Structural Database: a quarter of a million crystal structures and rising [J].

Allen, FH .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 2002, 58 (3 PART 1) :380-388

[2] STRUCTURES OF TETRAKIS(2-AMINO-6-METHYLPYRIDINIUM) CATENA-BIS(ACETONITRILE)-TETRADECA-MU-CHLORO-PENTANICKELATE(II) AND BIS(3-PICOLINIUM) CATENA-DIAQUAOCTA-MU-CHLORO-TRINICKELATE(II) [J].

BOND, MR ;

WILLETT, RD .

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1993, 49 :861-865

[3]

*BRUK AXS INC, 1998, SMART VERS 5 059

[4]

*BRUK AXS INC, 1999, SAINT PLUS VERS 6 02

[5] Structural and electrical characterization of polymeric haloplumbate(II) systems [J].

Corradi, AB ;

Ferrari, AM ;

Pellacani, GC ;

Saccani, A ;

Sandrolini, F ;

Sgarabotto, P .

INORGANIC CHEMISTRY, 1999, 38 (04) :716-721

[6]

Corradi AB, 2001, INORG CHEM, V40, P218

[7]

Gröger H, 2002, Z ANORG ALLG CHEM, V628, P57, DOI 10.1002/1521-3749(200201)628:1<57::AID-ZAAC57>3.0.CO

[8]

2-P

[9] Synthesis and crystal structures of polymeric iodoplumbate chains and nets [J].

Krautscheid, H ;

Vielsack, F .

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1997, 623 (02) :259-263

[10] Synthesis and crystal structures of iodoplumbate chains, ribbons and rods with new structural types [J].

Krautscheid, H ;

Lode, C ;

Vielsack, F ;

Vollmer, H .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (07) :1099-1104

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