Tetrakis[(9-oxo-10-thiaxanthen-2-yl-oxyethyl)ammonium] decaiodotriplumbate(II)

被引：8

作者：

Maxcy, KR ^{[1
]}

Willett, RD

Mitzi, DB

Afzali, A

机构：

[1] Washington State Univ, Dept Chem, Pullman, WA 99164 USA

[2] IBM Corp, Thomas J Watson Res Ctr, Yorktown Hts, NY 10598 USA

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2003年 / 59卷

关键词：

D O I：

10.1107/S1600536803007414

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The structure of the title compound, (AETO)(4)[Pb3I10] or (C15H14NO2S)(4)[Pb3I10], contains chains of octahedrally coordinated PbI6 species along with two crystallographically independent AETO cations that hydrogen bond to these chains. Individual (Pb3I10)(n)(4n-). chains are linked into layers via hydrogen bonds. The cations sheath each layer of chains, forming cation-chain-cation triple layers. Cations on adjacent triple layers interdigitate, forming stacks running parallel to [110]. There is a range of hydrogen bonding interactions between each cation and the (Pb3I10)(n)(4n-). chains.

引用

页码：M364 / M366

页数：3