Hexamethylenetetramine: A new fuel for solution combustion synthesis of complex metal oxides

被引：68

作者：

Prakash, AS

Khadar, AMA

Patil, KC

Hegde, MS ^{[1
]}

机构：

[1] Indian Inst Sci, Solid State & Struct Chem Unit, Bangalore 560012, Karnataka, India

[2] Mangalore Univ, Dept Chem, Mangalore 574199, India

[3] Indian Inst Sci, Dept Inorgan & Phys Chem, Bangalore 560012, Karnataka, India

来源：

JOURNAL OF MATERIALS SYNTHESIS AND PROCESSING | 2002年 / 10卷 / 03期

关键词：

metal oxides; hexamethylenetetramine; solution combustion synthesis;

D O I：

10.1023/A:1021986613158

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Hexamethylenetetramine, (CH2)(6)N-4 (HMT) has been employed as a fuel for the first time to synthesize several binary, ternary, and quaternary oxides by the solution combustion method. Technologically important oxides, namely, zirconia, ceria, and their solid solutions, alpha-Al2O3, Cr3+-doped alpha-Al2O3, spinels, MAl2O4 (M = Ca, Mg, Zn and Ni), perovskites, LaMO3 (M = Mn, Cr and Al), La0.67Sr0.33MnO3, and La0.67Ca0.33MnO3, have been synthesized. The oxides synthesized are characterized by X-ray powder diffraction, resistivity, fluorescence spectra, particle size, and surface area measurements. Decomposition of nickel nitrate-HMT complex has been investigated by TG, DTA, TPD, and evolved-gas analysis to elucidate the mechanism.

引用

页码：135 / 141

页数：7

共 24 条

[1] ZIRCONIUM PHOSPHO-SULFATES WITH NAZR2(PO4)3-TYPE STRUCTURE [J].