Building molecular minerals: All ferric pieces of molecular magnetite

被引：75

作者：

Powell, GW

Lancashire, HN

Brechin, EK

Collison, D

Heath, SL

Mallah, T

Wernsdorfer, W

机构：

[1] Univ Edinburgh, Sch Chem, Edinburgh EH9 3JJ, Midlothian, Scotland

[2] Univ Paris 11, UMR 8613, CNRS, F-91405 Orsay, France

[3] CNRS, Lab Louis Neel, F-38042 Grenoble 9, France

[4] Univ Manchester, Dept Chem, Manchester M13 9PL, Lancs, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 43期

关键词：

cluster compounds; hydrolysis; iron; magnetic properties; single-molecule magnets;

D O I：

10.1002/anie.200460636

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Mimicking magnetic minerals: Controlled hydrolysis of iron(III) salts leads to all-ferric molecular fragments with the iron and oxygen topology of magnetite and large spin ground states (see structure; yellow Fe, red O, blue N, gray C).

引用

页码：5772 / 5775

页数：4

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