Boron in granitic magmas: stability of tourmaline in equilibrium with biotite and cordierite

Experiments at 750 degrees C, 200 MPa(H2O), a((H2O)) = 1, and f(O2)similar to Ni-NiO established that the equilibrium among tourmaline, biotite, cordierite, and melt (+/- spinel, aluminosilicate, or corundum) occurs with similar to 2 wt% B2O3 in strongly peraluminous melt with an aluminosity, measured by the parameter ASI, of > 1.2. The experiments demonstrate the relationship of tourmaline stability to the activity product of the tourmaline components boron and aluminum, which are inversely related to one another. Tourmaline is unstable in metaluminous to mildly peraluminous melts (ASI < 1.2) at 750 degrees C regardless of their baron content. For a given aluminosity, addition of components such as F requires a greater boron content of melt at this equilibrium. The stability of tourmaline increases with decreasing temperatures below 750 degrees C. At the inception of melting, tourmaline breaks down incongruently to assemblages containing crystalline AFM silicates (biotite, cordierite, garnet, sillimanite), aluminates (spinel, corundum), and B-enriched but Fe-Mg-poor melt. Granitic melts are likely to be undersaturated in tourmaline horn the start of their crystallization, and their initial boron contents will be limited by the abundance of tourmaline in their source rocks. Quartzofeldspathic (gneissic, metapelitic) rocks that reached conditions of the granulite facies and still contain (prograde) tourmaline are rare, and probably have never yielded a partial melt. Most leucogranitic magmas will initially crystallize biotite, cordierite, or garnet, but not tourmaline. With crystallization, the Fe-Mg content of melt decreases, and the B2O3 content increases until the tourmaline-biotite and/or tourmaline-cordierite (or garnet) equilibria are attained. The B2O3 content of melt is buffered as long as these equilibria continue to operate. but low initial Fe-Mg contents of the magmas limit the quantity of boron that can be consumed by these reactions to <1 wt% B2O3. Normally, leucogranitic magmas contain insufficient Fe and Mg to conserve all boron as tourmaline and thus lose a large fraction of magmatic boron to wallrocks. Leucogranites and pegmatites with tourmaline as an early and only AFM silicate mineral probably contained >2 wt% B2O3 in their bulk magmas.