A relationship between Raman and infrared spectra: the case of push-pull molecules

被引：47

作者：

Del Zoppo, M ^{[1
]}

Tommasini, M ^{[1
]}

Castiglioni, C ^{[1
]}

Zerbi, G ^{[1
]}

机构：

[1] Politecn Milan, Dipartimento Chim Ind & Ingn Chim, I-20133 Milan, Italy

来源：

CHEMICAL PHYSICS LETTERS | 1998年 / 287卷 / 1-2期

关键词：

D O I：

10.1016/S0009-2614(98)00150-X

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Vibrational spectra of push-pull polyenes show a peculiar feature namely, in infrared and Raman spectra strong, coincident bands appear, arising from vibrations localised on the polyene bridge. A simple model, based on the introduction of an effective internal field due to the charge transfer between end groups allows the infrared and Raman intensities of these bands to be related. (C) 1998 Elsevier Science B.V. All rights reserved.

引用

页码：100 / 108

页数：9

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