Preparation of a novel indium hydride and application to practical organic synthesis

被引：69

作者：

Miyai, T ^{[1
]}

Inoue, K ^{[1
]}

Yasuda, M ^{[1
]}

Shibata, I ^{[1
]}

Baba, A ^{[1
]}

机构：

[1] Osaka Univ, Fac Engn, Dept Appl Chem, Osaka 565, Japan

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 14期

关键词：

D O I：

10.1016/S0040-4039(98)00050-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Dichloroindium hydride was first generated using the transmetalation between indium trichloride and tributylstannane at -78 degrees C, and the generation was confirmed by IR and NMR measurements. The resulting hydride is considerably stable even at ambient temperature due to the coordination of THF, such that it is applicable to practical reduction of carbonyls and halides. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：1929 / 1932

页数：4

共 30 条

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