Size dependence of solvation Gibbs energies: A critique and a rebuttal of some recent publications

被引：26

作者：

Ben-Naim, A ^{[1
]}

Mazo, R

机构：

[1] Hebrew Univ Jerusalem, Dept Phys Chem, IL-91904 Jerusalem, Israel

[2] Univ Oregon, Inst Theoret Sci, Eugene, OR 97403 USA

来源：

JOURNAL OF PHYSICAL CHEMISTRY B | 1997年 / 101卷 / 51期

关键词：

D O I：

10.1021/jp970257s

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The definition of the solvation Gibbs energy of a solute A in any solvent is repeated in exactly the same way as was done almost 20 years ago. Some recent publications that challenged this definition and suggestion "correction" terms; are critically examined. It is shown that these newly suggested quantities are irrelevant to the solvation process.

引用

页码：11221 / 11225

页数：5

共 19 条

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