Single chain magnet behaviour in an enantiopure chiral cobalt(II)-copper(II) one-dimensional compound

被引：99

作者：

Pardo, Emilio ^{[1
]}

Train, Cyrille ^{[1
]}

Lescouezec, Rodrigue ^{[1
]}

Journaux, Yves ^{[1
]}

Pasan, Jorge ^{[2
]}

Ruiz-Perez, Catalina ^{[2
]}

Delgado, Fernando S. ^{[3
]}

Ruiz-Garcia, Rafael ^{[4
]}

Lloret, Francesc ^{[4
]}

Paulsen, Carley ^{[5
]}

机构：

[1] Univ Paris 06, Inst Parisien Chim Mol, UMR 7071, F-75005 Paris, France

[2] Univ La Laguna, Dept Fis Fundamental 1, Lab Rayos & Mat Mol X, Tenerife 38201, Spain

[3] European Synchrotron Radiat Facil, BM16, F-38043 Grenoble 9, France

[4] Univ Valencia, ICMOL, Dept Quim Inorgan, Valencia 46980, Spain

[5] CNRS, Inst Neel, F-38042 Grenoble 9, France

来源：

CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 13期

关键词：

DESIGN; LIGAND;

D O I：

10.1039/b920231e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The self-assembly of an enantiomerically pure, chiral dianionic oxamatocopper(II) complex with cobalt(II) ions leads to neutral oxamato-bridged heterobimetallic chains that combine chirality and slow magnetic relaxation, providing thus the first example of "chiral single chain magnets" (CSCMs).

引用

页码：2322 / 2324

页数：3

共 21 条

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[3]

2-U

[4]

CANESCHI A, 2001, ANGEW CHEM, V113, P1810