Amorphous Carbon Nanofibers and Their Activated Carbon Nanofibers as Supercapacitor Electrodes

被引：236

作者：

Barranco, V. ^{[1
]}

Lillo-Rodenas, M. A. ^{[2
]}

Linares-Solano, A. ^{[2
]}

Oya, A. ^{[3
]}

Pico, F. ^{[4
]}

Ibanez, J. ^{[4
]}

Agullo-Rueda, F. ^{[1
]}

Amarilla, J. M. ^{[1
]}

Rojo, J. M. ^{[1
]}

机构：

[1] CSIC, ICMM, E-28049 Madrid, Spain

[2] Univ Alicante, Dept Quim Inorgan, MCMA, E-03080 Alicante, Spain

[3] Gunma Univ, Fac Engn, Kiryu, Gunma 376, Japan

[4] CSIC, CENIM, E-28040 Madrid, Spain

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2010年 / 114卷 / 22期

关键词：

DOUBLE-LAYER CAPACITANCE; CHEMICAL ACTIVATION; COMPOSITES; GROWTH; KOH;

D O I：

10.1021/jp1021278

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Carbon nanofibers (CNFs) show a high electrical conductivity but a reduced specific surface area that limits their use as electrode materials for supercapacitors. In this work, amorphous CNFs, with a relatively high electrical conductivity are easily activated in KOH, using certain KOH/CNF weight ratios. Activation does not produce any important change in the shape, surface roughness, diameter, graphene sheet size, and electrical conductivity of starting nanofibers. However, activation leads to new micropores and larger surface areas as well as a higher content of basic oxygen groups. They clearly enhanced the specific capacitance, attaining values higher than those reported for other activated CNFs. In this study, the effects of micropore size and oxygen content on the specific capacitance are discussed for three electrolytes: H2SO4, KOH, and (CH3CH2)(4)NBF4. Moreover, a good cycle life is found for the most activated CNFs.

引用

页码：10302 / 10307

页数：6

共 49 条

[1] Application of electrochemically prepared carbon nanofibers in supercapacitors [J].