Lipase-catalyzed ring-opening polymerization of lactide

被引：101

作者：

Matsumura, S

Mabuchi, K

Toshima, K

机构：

[1] Faculty of Science and Technology, Keio University, Kohoku-ku, Yokohama 223, 3-14-1, Hiyoshi

来源：

MACROMOLECULAR RAPID COMMUNICATIONS | 1997年 / 18卷 / 06期

关键词：

D O I：

10.1002/marc.1997.030180604

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The six-membered lactide was polymerized using the ring-opening polymerization with lipase as a catalyst at a temperature between 80 and 130 degrees C in bulk to yield the corresponding polylactide with weight-average molecular weights of up to 126 000. The most preferable conditions with respect to the molecular weight of the polylactide are the bulk polymerization using lipase PS at a temperature of 100 degrees C. The D,L-lactide gave higher molecular weight compared to the D,D- and L,L-lactide.

引用

页码：477 / 482

页数：6

共 24 条

[21] STEREOCOMPLEX FORMATION BETWEEN ENANTIOMERIC POLY(LACTIC ACID) .8. COMPLEX FIBERS SPUN FROM MIXED-SOLUTION OF POLY(D-LACTIC ACID) AND POLY(L-LACTIC ACID) [J].