A new lead(II) inorganic-organic hybrid of the P,P′-diphenylmethylene-diphosphinate ligand:: Synthesis and X-ray characterization of the [Pb(CH2(P(Ph)O2)2)] complex

被引：27

作者：

Cecconi, F ^{[1
]}

Ghilardi, CA ^{[1
]}

Midollini, S ^{[1
]}

Orlandini, A ^{[1
]}

机构：

[1] CNR, ICCOM, I-50132 Florence, Italy

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 05期

关键词：

inorganic-organic hybrids; crystal structures; polymeric complexes; lead complexes;

D O I：

10.1016/S1387-7003(03)00037-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By reaction of lead(II) nitrate with P, P'-diphenylmethylenediphosphinic acid in water solution a new inorganic-organic hybrid of formula [Pb(CH2(P(Ph)O-2)(2))] has been synthesized and structurally characterized. The complex displays a polymeric columnar structure, the column being formed by two intersecting sinusoidal ribbons of lead(II) ions bridged by bifunctional phosphinate ligands. The intersections of the ribbons are constituted by dimeric units of pentacoordinated lead(II) ions. (C) 2003 Elsevier Science B.V. All rights reserved.

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页码：546 / 548

页数：3

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