The first unambiguous determination of a nitrosyl-to-nitrite conversion in an iron nitrosyl porphyrin

被引：53

作者：

Cheng, L

Powell, DR

Khan, MA

Richter-Addo, GB

机构：

[1] Univ Oklahoma, Dept Chem & Biochem, Norman, OK 73019 USA

[2] Univ Wisconsin, Dept Chem, Xray Struct Lab, Madison, WI 53706 USA

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 23期

关键词：

D O I：

10.1039/b006775j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The picket fence porphyrin complex [Fe(tpivpp)(NO)] undergoes complete conversion to the isolable N-bound nitrite derivative [Fe(tpivpp)(NO2)(py)] in air in the presence of pyridine: reconversion to the starting nitrosyl complex is achieved using triphenylphosphine as reductant.

引用

页码：2301 / 2302

页数：2

共 14 条

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