Synthesis of enantiomerically pure C2-symmetric acyclic and cyclic 1,2-diamines via pinacol coupling of imines

被引：46

作者：

Annunziata, R ^{[1
]}

Benaglia, M ^{[1
]}

Caporale, M ^{[1
]}

Raimondi, L ^{[1
]}

机构：

[1] Univ Milan, Dipartimento Chim Organ & Ind, I-20133 Milan, Italy

来源：

TETRAHEDRON-ASYMMETRY | 2002年 / 13卷 / 24期

关键词：

D O I：

10.1016/S0957-4166(02)00748-6

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The inter- and intramolecular coupling of imines promoted by samarium diiodide and Lewis acids or by Zn/MsOH was extensively studied. The intramolecular reaction of chiral, enantiomerically pure bis-imines was also considered, and allowed the efficient, stereoselective synthesis of 1,2-diamines with C-2-symmetry. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：2727 / 2734

页数：8

共 44 条

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