Polyhydrido(silylene)osmium and silyl(dinitrogen)ruthenium products through redistribution of phenylsilane with osmium and ruthenium pincer complexes

被引：59

作者：

Gusev, DG ^{[1
]}

Fontaine, FG

Lough, AJ

Zargarian, D

机构：

[1] Wilfrid Laurier Univ, Dept Chem, Waterloo, ON N2L 3C5, Canada

[2] Univ Toronto, Dept Chem, Xray Lab, Toronto, ON M5S 3H6, Canada

[3] Univ Montreal, Dept Chim, Montreal, PQ H3C 3J7, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 02期

关键词：

hydrides; osmium; pincer ligands; silanes; silylene ligands;

D O I：

10.1002/anie.200390082

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Migration/Redistribution Galore! The reaction of phenylsilane with a series of Os and Ru pincer complexes has led to the isolation of complexes 1-3, thus allowing the direct observation of 1,2-addition and redistribution reactions that are so fundamental in the transformations of organosilanes in catalysis. Complex 1 represents a rare example of a complex containing a donor-stabilized SiH2 ligand.

引用

页码：216 / +

页数：5

共 40 条

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