Polyhydrido(silylene)osmium and silyl(dinitrogen)ruthenium products through redistribution of phenylsilane with osmium and ruthenium pincer complexes

被引:59
作者
Gusev, DG [1 ]
Fontaine, FG
Lough, AJ
Zargarian, D
机构
[1] Wilfrid Laurier Univ, Dept Chem, Waterloo, ON N2L 3C5, Canada
[2] Univ Toronto, Dept Chem, Xray Lab, Toronto, ON M5S 3H6, Canada
[3] Univ Montreal, Dept Chim, Montreal, PQ H3C 3J7, Canada
关键词
hydrides; osmium; pincer ligands; silanes; silylene ligands;
D O I
10.1002/anie.200390082
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Migration/Redistribution Galore! The reaction of phenylsilane with a series of Os and Ru pincer complexes has led to the isolation of complexes 1-3, thus allowing the direct observation of 1,2-addition and redistribution reactions that are so fundamental in the transformations of organosilanes in catalysis. Complex 1 represents a rare example of a complex containing a donor-stabilized SiH2 ligand.
引用
收藏
页码:216 / +
页数:5
相关论文
共 40 条