Brilliant reversible luminescent mechanochromism of silver(I) complexes containing o-bis(diphenylphosphino)benzene and phosphinesulfide

被引:110
作者
Tsukuda, Toshiaki [1 ]
Kawase, Marina [1 ]
Dairiki, Ayumi [1 ]
Matsumoto, Kenji [1 ]
Tsubomura, Taro [1 ]
机构
[1] Seikei Univ, Dept Mat & Life Sci, Tokyo 1808633, Japan
关键词
CU(I) COMPLEXES; LIGAND; MONONUCLEAR; COPPER(I); EMISSION; SERIES;
D O I
10.1039/b921111j
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The Ag(I) complex with o-bis(diphenylphosphino)benzene shows reversible interconversion between blue-emitting (1b) and green-emitting (1g) materials on grinding and heating; comparison of the structure of 1b with another green-emitting crystals (2) having the same formula suggests the chromism results from intermolecular interactions between adjacent phenylene rings.
引用
收藏
页码:1905 / 1907
页数:3
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