Controlled synthesis of ZnO nanocrystals with column-, rosette- and fiber-like morphologies and their photoluminescence property

被引:12
作者
Zou, GF
Yu, DB
Wang, DB
Zhang, WQ
Xu, LQ
Yu, WC
Qian, YT [1 ]
机构
[1] Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China
[2] Univ Sci & Technol China, Struct Res Lab, Hefei 230026, Peoples R China
基金
中国国家自然科学基金;
关键词
annealing; thermogravimetric analysis (TGA); oxides; luminescence;
D O I
10.1016/j.matchemphys.2004.06.033
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
ZnO nanocrystals with column-, rosette- and fiber-like morphologies have been synthesized by annealing their precursors at 550degreesC under ambient pressure. The precursors were prepared via a hydrothermal process using different starting materials. The products were characterized using XRD, XPS, DT-TG, SEM and PL techniques. It was found the morphologies of ZnO nanocrystals have significant effect on their luminescent properties in particular the strength of luminescence. Besides the emissions at ca. 390 and 490 nm, the rosette- and fiber-like ZnO nanocrystals have an additional emission at ca. 425 nm. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:150 / 154
页数:5
相关论文
共 44 条
[1]   Semiconductor clusters, nanocrystals, and quantum dots [J].
Alivisatos, AP .
SCIENCE, 1996, 271 (5251) :933-937
[2]   X-ray diffraction study of the early stages of the growth of nanoscale zinc oxide crystallites obtained from thermal decomposition of four precursors. General concepts on precursor-dependent microstructural properties [J].
Audebrand, N ;
Auffredic, JP ;
Louer, D .
CHEMISTRY OF MATERIALS, 1998, 10 (09) :2450-2461
[3]   Optically pumped lasing of ZnO at room temperature [J].
Bagnall, DM ;
Chen, YF ;
Zhu, Z ;
Yao, T ;
Koyama, S ;
Shen, MY ;
Goto, T .
APPLIED PHYSICS LETTERS, 1997, 70 (17) :2230-2232
[4]  
Boyle DS, 2002, CHEM COMMUN, P80, DOI 10.1039/b110079n
[5]   Synthesis, isolation, and chemical reactivity studies of nanocrystalline zinc oxide [J].
Carnes, CL ;
Klabunde, KJ .
LANGMUIR, 2000, 16 (08) :3764-3772
[6]   UNIFORM PARTICLES OF ZINC-OXIDE OF DIFFERENT MORPHOLOGIES [J].
CHITTOFRATI, A ;
MATIJEVIC, E .
COLLOIDS AND SURFACES, 1990, 48 (1-3) :65-78
[7]   Characteristics of sol-gel synthesis of ZnO-based powders [J].
Chu, SY ;
Yan, TM ;
Chen, SL .
JOURNAL OF MATERIALS SCIENCE LETTERS, 2000, 19 (04) :349-352
[8]   The effect of Zn buffer layer on growth and luminescence of ZnO films deposited on Si substrates [J].
Fu, ZX ;
Lin, BX ;
Liao, GH ;
Wu, ZQ .
JOURNAL OF CRYSTAL GROWTH, 1998, 193 (03) :316-321
[9]  
Govender K, 2002, ADV MATER, V14, P1221, DOI 10.1002/1521-4095(20020903)14:17<1221::AID-ADMA1221>3.0.CO
[10]  
2-1