Preparation of carbon molecular sieve from lignocellulosic biomass: A review

被引：210

作者：

Mohamed, Abdul Rahman ^{[1
]}

Mohammadi, Maedeh ^{[2
]}

Darzi, Ghasem Najafpour ^{[2
]}

机构：

[1] Univ Sains Malaysia, Sch Chem Engn, Nibong Tebal 14300, Penang, Malaysia

[2] Noushirvani Univ Technol, Fac Chem Engn, Babol Sar, Iran

来源：

RENEWABLE & SUSTAINABLE ENERGY REVIEWS | 2010年 / 14卷 / 06期

关键词：

Activated char; Carbon molecular sieve; Lignocellulosic biomass; Selectivity; OIL-PALM SHELL; ACTIVATED CARBON; CHEMICAL ACTIVATION; CARBONIZATION TEMPERATURE; AGRICULTURAL RESIDUES; EUCALYPTUS-GLOBULUS; CO2; ACTIVATION; PORE SIZES; PYROLYSIS; COCONUT;

D O I：

10.1016/j.rser.2010.01.024

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

A literature review on preparation of carbon molecular sieve (CMS) from lignocellulosic biomass is presented. The effect of various operation parameters such as pyrolytic temperature, flow rate of the carbonizing agent and time of pyrolysis on the carbonization of the lignocellulosic biomass as a carbon precursor was reviewed. Various physical and chemical processes for the activation of the biomass-based char and their effects on textural properties of the activated char were discussed. Conversion of activated chars to CMS as the final stage of the preparation process through different techniques of chemical vapor deposition (CVD) and controlled pyrolysis was assessed. Survey of literature revealed that production of CMS with BET surface area of 1247 m(2)/g and micropore volume of 0.51 cm(3)/g, under appropriate conditions has been reported. Also, maximum selectivity of 7.6 and 400 for separation of O-2/N-2 and CO2/CH4 was devoted to palm shell and coconut shell-based CMS, respectively. (C) 2010 Elsevier Ltd. All rights reserved.

引用

页码：1591 / 1599

页数：9

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