The first thorium arene complex: A divalent synthon

被引：87

作者：

Korobkov, I ^{[1
]}

Gambarotta, S ^{[1
]}

Yap, GPA ^{[1
]}

机构：

[1] Univ Ottawa, Dept Chem, Ottawa, ON K1N 6N5, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 07期

关键词：

actinides; arene ligands; macrocyclic ligands; N ligands; thorium;

D O I：

10.1002/anie.200390217

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly reactive thorium naphthalene complex, namely 1-[Li(dme)3] was prepared by reducing a ThIV precursor with Li(naphthalene). The complex behaves as a synthon for ThII and reacts with Me3SiN3 to give the thorium silazanate 2.

引用

页码：814 / 818

页数：5

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