3,6-di(azido)-1,2,4,5-tetrazine: A precursor for the preparation of carbon nanospheres and nitrogen-rich carbon nitrides

被引：108

作者：

Huynh, MHV

Hiskey, MA

Archuleta, JG

Roemer, EL

Gilardi, R

机构：

[1] Los Alamos Natl Lab, Dynam Expt Div, Mat Dynam Grp, Los Alamos, NM 87545 USA

[2] USN, Res Lab, Struct Matter Lab, Washington, DC 20375 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 42期

关键词：

azides; carbon; nanostructures; nitrides; nitrogen;

D O I：

10.1002/anie.200460708

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A high-nitrogen compound, 3,6-di(azido)-1,2,4,5-tetrazine, was used as precursor for the preparation of carbon nanospheres (see SEM picture) and nitrogen-rich carbon nitrides. The conversions into both carbon-based materials are simple, occur under mild conditions (low temperature, no applied pressure), and require no vacuum systems, extraction, carbonization, and purification.

引用

收藏

页码：5658 / 5661

页数：4

相关论文

共 52 条

[1]

ARMOR JN, 1995, ADV CHEM SER, P245

[2] TEMPERATURE-DEPENDENCE OF THERMAL MOTION IN CRYSTALLINE NAPHTHALENE [J].

BROCK, CP ;

DUNITZ, JD .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1982, 38 (AUG) :2218-2228

[3] Forming silicon carbon nitride crystals and silicon carbon nitride nanotubes by microwave plasma-enhanced chemical vapor deposition [J].

Chang, HL ;

Hsu, CM ;

Kuo, CT .

APPLIED PHYSICS LETTERS, 2002, 80 (24) :4638-4640

[4] Anodic performances of mesocarbon microbeads (MCMB) prepared from synthetic naphthalene isotropic pitch [J].

Chang, YC ;

Sohn, HJ ;

Ku, CH ;

Wang, YG ;

Korai, Y ;

Mochida, I .

CARBON, 1999, 37 (08) :1285-1297

[5] Synthesis of the bi-heterocyclic parent ring system 1,2,4-triazolo[4,3-b][1,2,4,5]tetrazine and some 3,6-disubstituted derivatives [J].

Chavez, DE ;

Hiskey, MA .

JOURNAL OF HETEROCYCLIC CHEMISTRY, 1998, 35 (06) :1329-1332

[6] AN IMPROVED SYNTHESIS OF 3,6-DIAMINO-1,2,4,5-TETRAZINE .2. FROM TRIAMINOGUANIDINE AND 2,4-PENTANEDIONE [J].

COBURN, MD ;

BUNTAIN, GA ;

HARRIS, BW ;

HISKEY, MA ;

LEE, KY ;

OTT, DG .

JOURNAL OF HETEROCYCLIC CHEMISTRY, 1991, 28 (08) :2049-2050

[7] A review of investigations on biocompatibility of diamond-like carbon and carbon nitride films [J].

Cui, FZ ;

Li, DJ .

SURFACE & COATINGS TECHNOLOGY, 2000, 131 (1-3) :481-487

[8]

DASGUPTA S, 2001, Patent No. 6261722

[9] Polymeric ion-exchange fibers [J].

Economy, J ;

Dominguez, L ;

Mangun, CL .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2002, 41 (25) :6436-6442

[10] Synthesis of nitrogen-rich carbon nitride networks from an energetic molecular azide precursor [J].

Gillan, EG .

CHEMISTRY OF MATERIALS, 2000, 12 (12) :3906-3912

← 1 2 3 4 5 6 →