3,6-di(azido)-1,2,4,5-tetrazine: A precursor for the preparation of carbon nanospheres and nitrogen-rich carbon nitrides

被引：108

作者：

Huynh, MHV

Hiskey, MA

Archuleta, JG

Roemer, EL

Gilardi, R

机构：

[1] Los Alamos Natl Lab, Dynam Expt Div, Mat Dynam Grp, Los Alamos, NM 87545 USA

[2] USN, Res Lab, Struct Matter Lab, Washington, DC 20375 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 42期

关键词：

azides; carbon; nanostructures; nitrides; nitrogen;

D O I：

10.1002/anie.200460708

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A high-nitrogen compound, 3,6-di(azido)-1,2,4,5-tetrazine, was used as precursor for the preparation of carbon nanospheres (see SEM picture) and nitrogen-rich carbon nitrides. The conversions into both carbon-based materials are simple, occur under mild conditions (low temperature, no applied pressure), and require no vacuum systems, extraction, carbonization, and purification.

引用

页码：5658 / 5661

页数：4