The fabrication and linear optical characterization of a Bragg reflector in a planar polymeric waveguide, suitable for an all-optical switching device, is reported. Surface corrugation gratings with a grating constant of 339 nm were produced in different polymeric films of poly(phenylene-vinylene), polydiacetylene and polystyrene by excimer laser photoablation. Furthermore, the gap in the linear transmission spectrum of the modulated waveguide was measured and compared with the result of numerical simulations. A good agreement can only be found if a non-uniform grating with a small chirp is assumed. This small deviation from the uniform grating cannot be resolved with a scanning electron microscope. However, this linear optical investigation helps to further improve the fabrication process and opens the possibility to yield a well-defined grating with a prescribed modulation strength, which is a vital requirement for the proper operation of a nonlinear all-optical switch. (C) 1998 Elsevier Science B.V.