Mossbauer investigation of Sr1-xLaxFe12-yCOyO19 ferrites

被引:75
作者
Lechevallier, L
Le Breton, JM [1 ]
Teillet, J
Morel, A
Kools, F
Tenaud, P
机构
[1] Univ Rouen, UMR 6634 CNRS, Grp Phys Mat, F-76801 St Etienne, France
[2] Univ Cergy Pontoise, Lab Phys Mat & Surfaces, F-95031 Cergy Pontoise, France
[3] Carbone Lorraine Ferrites, F-27016 Evreux, France
[4] Carbone Lorraine Ferrites, F-38830 St Pierre dAllevard, France
关键词
SrFe12O19; hexaferrites; La-Co substitution; Mossbauer spectrometry;
D O I
10.1016/S0921-4526(02)01712-X
中图分类号
O469 [凝聚态物理学];
学科分类号
070205 ;
摘要
Sr1-xLaxFe12-yCOyO19 powders with y/x = 0.75 and x = 0.1, 0.2, 0.3, 0.4 were prepared according to a ceramic process. X-ray diffraction analysis shows that all the powders are of single, hexagonal M-type, phase. The Mossbauer investigation confirms that CO2+ substitutes for Fe3+ in both 4f(2), (mainly) and 2a sites. The most important hyperfine parameters changes concern the 12k, 42 and 2b sites and are related to both CO2+/Fe3+ and La3+/Sr2+ substitution effects. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码:135 / 139
页数:5
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