Determination of charge carrier mobility of hole transporting polytriarylamine-based diodes

被引:24
作者
Barea, Eva M. [1 ]
Garcia-Belmonte, Germa [1 ]
Sommer, Michael [2 ]
Huettner, Sven [2 ]
Bolink, Henk J. [3 ]
Thelakkat, Mukundan [2 ]
机构
[1] Univ Jaume 1, Dept Fis, Photovolta & Optoelect Devices Grp, Castellon de La Plana 12071, Spain
[2] Univ Bayreuth, D-95440 Bayreuth, Germany
[3] Univ Valencia, Inst Mol Sci, Valencia 46980, Spain
关键词
Poly(triarylamines); Hole-transporting materials; Mobility; Organic electronics; LIGHT-EMITTING-DIODES; FIELD-EFFECT MOBILITY; SOLAR-CELLS; BLOCK-COPOLYMERS; TRANSIENT; PHOTOCONDUCTIVITY; TEMPERATURE; TRANSISTORS; POLYMERS; ELECTRON;
D O I
10.1016/j.tsf.2009.10.003
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Hole transport properties of three different side chain poly(triarylamines) have been determined by means of the analysis of steady-state current-voltage characteristics using co-planar diode structures. The interpretation is based on space-charge limited models with field-dependent mobility. Mobilities between similar to 10(-8) and 10(-6) cm(2) V-1 s(-1) are obtained. The highest mobility is achieved for poly(tetraphenylbenzidine) devices and the lowest for poly(triphenylamine) devices. Electron-rich methoxy substituents increase the mobility of poly(triphenylamine)s. A comparison of the mobility values with those obtained using organic field-effect transistors is also given. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:3351 / 3354
页数:4
相关论文
共 28 条
[21]   Synthesis, characterization and application of donor-acceptor block copolymers in nanostructured bulk heterojunction solar cells [J].
Sommer, M. ;
Thelakkat, M. .
EUROPEAN PHYSICAL JOURNAL-APPLIED PHYSICS, 2006, 36 (03) :245-249
[22]   Microphase-separated donor-acceptor diblock copolymers: Influence of HOMO energy levels and morphology on polymer solar cells [J].
Sommer, Michael ;
Lindner, Stefan M. ;
Thelakkat, Mukundan .
ADVANCED FUNCTIONAL MATERIALS, 2007, 17 (09) :1493-1500
[23]   PHOTOCONDUCTIVITY AND HOLE TRANSPORT IN POLYMERS OF AROMATIC AMINE-CONTAINING METHACRYLATES [J].
STOLKA, M ;
PAI, DM ;
RENFER, DS ;
YANUS, JF .
JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 1983, 21 (04) :969-983
[24]  
Sze S.M., 2013, SEMICONDUCTOR DEVICE
[25]   Unification of the hole transport in polymeric field-effect transistors and light-emitting diodes [J].
Tanase, C ;
Meijer, EJ ;
Blom, PWM ;
de Leeuw, DM .
PHYSICAL REVIEW LETTERS, 2003, 91 (21)
[26]  
Thelakkat M, 2002, MACROMOL MATER ENG, V287, P442, DOI 10.1002/1439-2054(20020701)287:7<442::AID-MAME442>3.0.CO
[27]  
2-H
[28]   Theory of the field-effect mobility in amorphous organic transistors [J].
Vissenberg, MCJM ;
Matters, M .
PHYSICAL REVIEW B, 1998, 57 (20) :12964-12967