η6-corannulene buckybowl complexes of iridium, including ring-to-ring migration

被引：52

作者：

Alvarez, CM

Angelici, RJ ^{[1
]}

Sygula, A

Sygula, R

Rabideau, PW

机构：

[1] Iowa State Univ, Dept Chem, Ames, IA 50011 USA

[2] Iowa State Univ, Ames Lab, Ames, IA 50011 USA

来源：

ORGANOMETALLICS | 2003年 / 22卷 / 04期

关键词：

CORANNULENE; FULLERENES; SURFACES; C-60;

D O I：

10.1021/om021012r

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Corannulene (C20H10, 1), a curved-surface fragment of buckminsterfullerene (C-60), forms an eta(6)-coordinated complex with Cp*Ir2+. The analogous 1,2,5,6-tetramethylcorannulene (2) complex, Cp*Ir(eta(6)-2)(2+), initially forms three isomers, but migration of the Cp*Ir2+ unit from a nonmethylated to a methylated ring gives two isomers in the final product.

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收藏

页码：624 / 626

页数：3

相关论文

共 17 条

[1] Reactions of transition metal complexes with fullerenes (C60, C70, etc.) and related materials [J].

Balch, AL ;

Olmstead, MM .

CHEMICAL REVIEWS, 1998, 98 (06) :2123-2165

[2] DIBENZO[GHI,MNO]FLUORANTHENE [J].

BARTH, WE ;

LAWTON, RG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1966, 88 (02) :380-&

[3]

Chen J., UNPUB

[4] THE CHEMICAL NATURE OF BUCKMINSTERFULLERENE (C60) AND THE CHARACTERIZATION OF A PLATINUM DERIVATIVE [J].

FAGAN, PJ ;

CALABRESE, JC ;

MALONE, B .

SCIENCE, 1991, 252 (5009) :1160-1161

[5] CRYSTAL AND MOLECULAR-STRUCTURE OF CORANNULENE, C-20H-10 [J].

HANSON, JC ;

NORDMAN, CE .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1976, 32 (APR15) :1147-1153

[6] Ru-3(CO)(9)(mu(3)-eta(2),eta(2),eta(2)-C-60): A cluster face-capping, arene-like complex of C-60 [J].

Hsu, HF ;

Shapley, JR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1996, 118 (38) :9192-9193

[7] The first fullerene-metal sandwich complex:: An unusually strong electronic communication between two C60 cages [J].

Lee, K ;

Song, H ;

Kim, B ;

Park, JT ;

Park, S ;

Choi, MG .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (12) :2872-2873

[8] Synthetic studies directed towards bucky-balls and bucky-bowls [J].

Mehta, G ;

Rao, HSP .

TETRAHEDRON, 1998, 54 (44) :13325-13370

[9] Buckybowls: Polynuclear aromatic hydrocarbons related to the buckminsterfullerene surface [J].

Rabideau, PW ;

Sygula, A .

ACCOUNTS OF CHEMICAL RESEARCH, 1996, 29 (05) :235-242

[10] Geodesic polyarenes with exposed concave surfaces [J].

Scott, LT ;

Bronstein, HE ;

Preda, DV ;

Ansems, RBM ;

Bratcher, MS ;

Hagen, S .

PURE AND APPLIED CHEMISTRY, 1999, 71 (02) :209-219