A two-dimensional framework of novel vanadium clusters bridged by [Ni(en)2]2+:: K{V12IVV6VO42Cl[Ni(en)2]3}•8H2O

被引：56

作者：

Pan, CL

Xu, JQ ^{[1
]}

Li, GH

Cui, XB

Ye, L

Yang, GD

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130023, Peoples R China

[2] Jilin Univ, Key Lab Supramol Struct & Spect, Changchun 130023, Peoples R China

来源：

DALTON TRANSACTIONS | 2003年 / 04期

关键词：

D O I：

10.1039/b211530c

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hydrothermal reaction of V2O5, H2C2O4.2H(2)O, en, KOH and NiCl2.6H(2)O gives a new two-dimensional open-framework solid; the extended structure consists of a two-dimensional network formed by the interconnection of each [V18O42Cl] cage to four other neighboring units via six [Ni(en)(2)](2+) bridging groups.

引用

页码：517 / 518

页数：2

共 23 条

[1]

Brown I.D., 1981, STRUCTURE BONDING CR, V2

[2] AN ORGANOMETAL HYDROXIDE ROUTE TO [(C5ME5)RH]4(V6O19) [J].