Amide alcoholysis in mononuclear zinc and cadmium complexes ligated by thioether sulfur and nitrogen donors

被引：42

作者：

Berreau, LM ^{[1
]}

Makowska-Grzyska, MM

Arif, AM

机构：

[1] Utah State Univ, Dept Chem & Biochem, Logan, UT 84322 USA

[2] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA

来源：

INORGANIC CHEMISTRY | 2000年 / 39卷 / 20期

关键词：

D O I：

10.1021/ic000547e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of divalent zinc and cadmium complexes ([(beppa)Zn](ClO4)2 (1), [(bmppa)Zn](ClO4)2 (2), and [(bmppa)Cd(ClO4)](ClO4)·MeOH (3)) of amide-appended N2S2 ligands (beppa = N-bis-2-(ethylthio)ethyl-N-(6-pivaloylamido-2-pyridylmethyl)amine; bmppa = N-bis-2-(methylthio)ethyl-N-(6-pivaloylamido-2-pyridylmethyl)amine) have been synthesized and characterized. Treatment of these complexes with 1 equiv of Me4NOH·5H2O in MeOH results in quantitative amide alcoholysis.

引用

页码：4390 / 4391

页数：2

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