Investigations into the mechanism of action of nitrobenzene as a mild dehydrogenating agent under acid-catalysed conditions

被引：19

作者：

Cristiano, MLS

Gago, DJP

Gonsalves, AMDR

Johnstone, RAW

McCarron, M

Varejao, JMTB

机构：

[1] Univ Liverpool, Dept Chem, Liverpool L69 3BX, Merseyside, England

[2] Univ Algarve, FCT, P-8000 Faro, Portugal

[3] Univ Coimbra, Dept Quim, P-3000 Coimbra, Portugal

[4] IPC, Escola Super Agr, P-3040 Coimbra, Portugal

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2003年 / 1卷 / 03期

关键词：

D O I：

10.1039/b210887a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Protonated nitrobenzene can be used to dehydrogenate a range of hydrocarbons, which already possess at least one double bond. Kinetic and spectroscopic results, together with known electrode potentials, yield approximate limits within which protonated nitrobenzenes can be expected to effect dehydrogenation of hydroaromatic compounds. A high yielding synthesis of benzo[j]fluoranthene is described.

引用

页码：565 / 574

页数：10

共 76 条

[61] AROMATIC CYCLODEHYDROGENATION .5. A SYNTHESIS OF FLUORANTHENE [J].