The origin of chemoselectivity in the hydrocarbonylation of alkenes catalysed by trialkylphosphine complexes of rhodium

被引：19

作者：

Cheliatsidou, P

White, DFS

Cole-Hamilton, DJ ^{[1
]}

机构：

[1] Univ St Andrews, Sch Chem, St Andrews KY16 9ST, Fife, Scotland

[2] Lyondell Chem Co, Newtown Sq, PA 19073 USA

来源：

DALTON TRANSACTIONS | 2004年 / 21期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1039/b412919a

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The formation of monophosphine acyl intermediates explains why PPr3i and PBu3i generate aldehydes in alkene hydrocarbonylation reactions carried out in protic solvents, whilst PEt3, for which the acyl complex contains two phosphines, produces alcohols.

引用

页码：3425 / 3427

页数：3

共 12 条

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