Formation of α-Mn2O3 nanorods via a hydrothermal-assisted cleavage-decomposition mechanism

被引：49

作者：

Chen, Youcun

Zhang, Yuanguang ^{[1
]}

Yao, Qi-Zhi

Zhou, Gen-Tao

Fu, Shengquan

Fan, Hai

机构：

[1] Anqing Normal Coll, Prov Key Lab Funct Coordinat Cpds, Anqing 246011, Peoples R China

[2] Anqing Normal Coll, Dept Chem, Anqing 246011, Peoples R China

[3] Univ Sci & Technol China, Dept Chem, Hefei 230026, Peoples R China

[4] Univ Sci & Technol China, Sch Earth & Space Sci, Hefei 230026, Peoples R China

来源：

JOURNAL OF SOLID STATE CHEMISTRY | 2007年 / 180卷 / 04期

基金：

中国国家自然科学基金;

关键词：

manganese oxides; hydrothermal synthesis; nanorod; mechanism;

D O I：

10.1016/j.jssc.2007.01.017

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A hydrothermal cleavage-decomposition mechanism was used to synthesize single-crystal alpha-Mn2O3 nanorods at 160 degrees C for 16 h using KMnO4 as manganese source and CTAB as reducing regent. The as-synthesized products were characterized by powder X-ray diffraction, transmission electron microscopy, high-resolution transmission electron microscopy and infrared spectrum. The results indicate that the reaction temperature is a crucial factor for the formation of alpha-Mn2O3 nanorods. These nanorods exhibit single-crystal nature, and have an average diameter of 36 nm and lengths of up to I mt. Based on our experimental results, a hydrothermal cleavage-decomposition mechanism has been proposed on the formation of alpha-Mn2O3 nanorods. (C) 2007 Elsevier Inc. All rights reserved.

引用

页码：1218 / 1223

页数：6

共 27 条

[1] Characterization of manganese and iron oxides as combustion catalysts for propane and propene [J].