Palladium-Catalyzed Carbonylation/Acyl Migratory Insertion Sequence

被引：140

作者：

Zhang, Zhenhua

Liu, Yiyang

Gong, Mingxing

Zhao, Xiaokun

Zhang, Yan

Wang, Jianbo ^{[1
]}

机构：

[1] Peking Univ, Coll Chem, BNLMS, Minist Educ, Beijing 100871, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 06期

关键词：

carbenes; carbonylation; diazo compounds; migratory insertion; palladium; ALPHA-DIAZOCARBONYL COMPOUNDS; CROSS-COUPLING REACTIONS; CARBENE INSERTION; BENZYL BROMIDES; VINYL HALIDES; ARYL HALIDES; COMPLEXES; DIAZOESTERS; IODIDES;

D O I：

10.1002/anie.200906349

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Chemical Equation Presented On the move: A palladium-catalyzed reaction of aryl iodides, diazo compounds or N-tosylhyd razones, and carbon monoxide affords β-oxo esters or ketones/ enones (see scheme; DCE = l,2-dichloroethane). The products are delivered with high efficiency through the title sequence. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA,.

引用

页码：1139 / 1142

页数：4

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