Synthesis of novel N-linked porphyrin-phthalocyanine dyads

被引：62

作者：

Soares, Ana R. M.

Martinez-Diaz, M. Victoria

Bruckner, Anita

Pereira, Ana M. V. M.

Tome, Joao P. C.

Alonso, Cristina M. A.

Faustino, Maria A. F.

Neves, Maria G. P. M. S.

Tome, Augusto C.

Silva, Artur M. S.

Cavaleiro, Jose A. S.

Torres, Tomas

Guldi, Dirk M.

机构：

[1] Univ Aveiro, Dept Quim, P-3810193 Aveiro, Portugal

[2] Univ Autonoma Madrid, Dept Quim Organ, E-28049 Madrid, Spain

[3] Univ Erlangen Nurnberg, Inst Phys Chem, D-91058 Erlangen, Germany

来源：

ORGANIC LETTERS | 2007年 / 9卷 / 08期

关键词：

D O I：

10.1021/ol0703635

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

[GRAPHICS] Two types of covalently NH-linked porphyrin-phthalocyanine dyads, connected either through the meso phenyl group or the beta-pyrrolic position of the porphyrin, have been synthesized following statistical condensation methodologies for phthalocyanine preparation and palladium-catalyzed amination methods. Photophysical studies have revealed that energy transfer from the porphyrin to the phthalocyanine prevails regardless of linkage.

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页码：1557 / 1560

页数：4

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