Decarbonylation of acetone and carbonate at a pincer-ligated Ru center

被引：53

作者：

Çelenligil-Çetin, R

Watson, LA

Guo, CY

Foxman, BM

Ozerov, OV

机构：

[1] Brandeis Univ, Dept Chem, Waltham, MA 02454 USA

[2] Earlham Coll, Richmond, IN 47374 USA

来源：

ORGANOMETALLICS | 2005年 / 24卷 / 02期

关键词：

D O I：

10.1021/om049061m

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A Ru center ligated by a pincer bis(o-phosphinoaryl)amine (PNP) ligand in (PNP)RuH(H-2) is sufficiently electron rich to break C-O and C-C bonds, resulting in the ultimate decarbonylation of hydrocarbonate and acetone, respectively, to give (PNP)RuH(CO). The decarbonylation of acetone is accompanied by hydrogenolysis of the C-C bonds to produce methane.

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页码：186 / 189

页数：4

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