Site-selective surface-initiated polymerization by Langmuir-Blodgett lithography

被引：41

作者：

Brinks, Marion K.

Hirtz, Michael

Chi, Lifeng

Fuchs, Harald

Studer, Armido

机构：

[1] Univ Munster, Inst Phys, D-48149 Munster, Germany

[2] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

[3] Univ Munster, NRW Grad Sch Chem, D-48149 Munster, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 27期

关键词：

atomic force microscopy; lithography; polymer brushes; radical polymerization; self-assembly;

D O I：

10.1002/anie.200605020

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Brushing the surface: Structured polymer brushes are readily prepared by site-selective immobilization of initiators in a self-assembly process by Langmuir-Blodgett lithography with subsequent polymerization. The AFM images show a DPPC/alkoxy amine LB film before and after surface-initiated controlled nitroxide-mediated radical polymerization. Large surface areas (several cm2) can readily be structured with this method. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：5231 / 5233

页数：3

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